Silica-Supported Perchloric Acid (HClO4-SiO2)
نویسندگان
چکیده
منابع مشابه
Graphite-supported perchloric acid (HClO4-C): an efficient and recyclable heterogeneous catalyst for the one-pot synthesis of amidoalkyl naphthols.
An efficient and direct protocol for the preparation of amidoalkylnaphthols employing a multi-component, one-pot condensation reaction of 2-naphthol, aromatic aldehydes and acetamide or benzamide in the presence of graphite supported perchloric acid under solvent-free conditions is described. The thermal solvent-free procedure offers advantages such as simple work-up, shorter reaction times and...
متن کاملHeats of formation of perchloric acid, HClO4, and perchloric anhydride, Cl2O7. Probing the limits of W1 and W2 theory
The heats of formation of HClO4 and Cl2O7 have been determined to chemical accuracy for the first time by means of W1 and W2 theory. These molecules exhibit particularly severe degrees of inner polarization, and as such obtaining a basis-set limit SCF component to the total atomization energy becomes a challenge. (Adding high-exponent d functions to a standard spd basis set has an effect on the...
متن کاملAnharmonic force fields of perchloric acid, HClO4, and perchloric anhydride, Cl2O7. An extreme case of inner polarization
DFT (density functional theory) anharmonic force fields with basis sets near the KohnSham limit have been obtained for perchloric acid, HClO4, and perchloric anhydride, Cl2O7. Calculated fundamental frequencies are in very good agreement with available experimental data. Some reassignments in the vibrational spectra of Cl2O7 are proposed based on our calculations. HClO4 and Cl2O7 are particular...
متن کاملReusable Silica supported Perchloric acid and potassium bisulphate as green catalysts for thiocyanation of aromatic compounds under solvent free conditions
Reusable silica supported perchloric acid and potassium bisulphate have been prepared and explored as green catalysts for thiocyanation of aromatic compounds under conventional and solvent free microwave assisted conditions. The microwave assisted protocol exhibited remarkable rate accelerations and offered selective thiocyanation of aromatic and hetero aromatic compounds in good yields. Reacti...
متن کاملExpedient Synthesis of the Pentasaccharide Repeating Unit of the Polysaccharide O‐Antigen of Escherichia coli O11
A convergent [3+2] block synthetic strategy was developed for the synthesis of the pentasaccharide repeating unit of the cell wall O-antigen of Escherichia coli O11 strain in excellent yield in a minimum number of steps. Several suitably functionalized thioglycoside derivatives were used as glycosyl donors during the synthesis of the target compound. A thioglycoside was the glycosyl donor used ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Synlett
سال: 2009
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-0029-1218338